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1 Glutathione’s main roles include: Neutralizing harmful free radicals and other reactive species Serving as a reducing substrate for antioxidant enzymes such as glutathione peroxidases Supporting the recycling of other antioxidants, including vitamin C and, indirectly, vitamin E Helping neutralize or metabolize certain reactive compounds and drug metabolites, including the reactive acetaminophen metabolite NAPQI Participating in Phase II detoxification reactions through glutathione conjugation Binding or conjugating with certain reactive compounds and metals, which may facilitate their metabolism, sequestration or elimination Regulating cellular proliferation and apoptosis Supporting mitochondrial redox balance and helping protect mitochondrial components, including mitochondrial DNA, from oxidative damage Essentially, glutathione helps protect cells against reactive oxygen and nitrogen species generated during normal metabolism and in response to certain environmental exposures

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